[1]高英,牛玉超*,段婷婷.PAA为模板纳米SiO2空心球及减反膜制备综述[J].山东建筑大学学报,2017,(04):365-372.
 Gao Ying,Niu Yuchao*,Duan Tingting.Review of hollow silica nanospheres and its antireflection coatings using PAA as template[J].,2017,(04):365-372.
点击复制

PAA为模板纳米SiO2空心球及减反膜制备综述()
分享到:

《山东建筑大学学报》[ISSN:1673-7644/CN:37-1449/TU]

卷:
期数:
2017年04期
页码:
365-372
栏目:
综合述评
出版日期:
2017-08-15

文章信息/Info

Title:
Review of hollow silica nanospheres and its antireflection coatings using PAA as template
文章编号:
1673-7644(2017)04-0365-08
作者:
高英牛玉超*段婷婷
(山东建筑大学 材料科学与工程学院,山东 济南 250101)
Author(s):
Gao Ying Niu Yuchao* Duan Tingting
(School of Material Science and Engineering, Shandong Jianzhu University, Jinan 250101, China)
关键词:
纳米SiO2空心球减反膜聚丙烯酸(PAA)模板
Keywords:
hollow silica nanospheres antireflection coatings polyacrylic acid (PAA) template
分类号:
TB34
文献标志码:
A
摘要:
纳米SiO2空心球及其减反膜由于其独特的结构特点和优良的性能受到越来越多的关注,应用越来越广泛,纳米SiO2空心球减反膜具有减反效果好、耐划伤、抗粘污、耐候性能优良等优点,使其在光学和太阳能光伏和光热等领域具有巨大的应用前景。文章简述了以PAA(聚丙烯酸)为模板的纳米SiO2空心球的制备方法,从催化剂NH3·H2O(氨水)、模板PAA和SiO2前驱体TEOS(正硅酸四乙酯)等3个方面分析了纳米SiO2空心球制备过程中的影响因素,阐明了模板核PAA的去除原理及去除方法;阐述了纳米SiO2空心球减反膜的制备技术,总结了纳米SiO2空心球减反膜溶胶的制备方法和减反膜的镀膜方法,分析了烧结对减反膜的作用;并对纳米SiO2空心球减反膜制备过程中存在的问题及其改善方法进行了展望。
Abstract:
The hollow silica nanospheres and its antireflection coatings are getting increasing attention for their distinct structural features and high performance, and they are more and more widely used. The hollow silica nanospheres antireflection coatings are especially used in optics, photovoltaics and optothermal widely for their good antireflection, dirt and scratch resistance and weather resistance. The preparation methods of hollow silica nanospheres using PAA as template are sketched, the influence factors of hollow silica nanospheres making process are analyzed from three aspects of catalyst ammomium hydroxide, template PAA and silica precursor TEOS, and the remove principle and methods of template PAA are expounded. The preparative technique of hollow silica nanospheres antireflection coatings is elaborated, the preparative methods of antireflection coatings sol and the coated methods of antireflaction coatings are summarized, and the calcine function to antireflection coatings is analyzed. The drawbacks existing in the preparation of hollow silica nanospheres antireflection coatings and their improving methods are forecasted.

参考文献/References:

[1] 谢运,薛汇丽,曾顺军.浅析单晶硅太阳能电池光电转换效率高于多晶硅太阳能电池的原因[J].中国科技投资,2016,154(16):188-188, 193.[2] Nostell P., Roos A., Karlsson B.. Antireflection of glazings for solar energy applications[J].Solar Energy Materials & Solar Cells,1998,54(1):223-233.[3] Shah L.J.. Heat transfer correlations for vertical mantle heat exchangers[J].Solar Energy,2001,69(1):157-171.[4] 李春华,姜宏,赵会峰,等.溶胶—凝胶法制备纳米多孔二氧化硅减反膜的研究进展[J].玻璃与搪瓷,2014,42(4):42-46.[5] Thomas I.M.. Method for the preparation of porous silica antireflection coatings varying in refractive index from 1.22 to 1.44[J].Applied Optics,1992,31(28):6145-6149.[6] Morikawa A., Iyoku Y., Kakimoto M.A., et al.. Preparation of silicacontaining polyvinylpyrrolidone films by solgel process[J].Polymer Journal,1992,24(7):689-692.[7] 田红,张磊,徐耀,等.PEG和PVP改性溶胶—凝胶二氧化硅减反膜的对比[J].物理化学学报,2012,28(5):1197-1205.[8] Guillemot F., BrunetBruneau A., BourgeatLami E., et al.. Latextemplated silica films: tailoring porosity to get a stable lowrefractive index[J].Chemistry of Materials,2010,22(9):2822-2828.[9] 高觉渊.苯基二氧化硅空心球及空心球/聚苯醚复合材料的制备与性能[D].广州:华南理工大学,2011.[10] Tissot I., Reymond J.P., Lefebvre F., et al.. SiOHfunctionalized polystyrene latexes: a step toward the synthesis of hollow silica nanoparticles[J]. Chemistry of Materials,2002,14(3):1325-1331.[11] Deng Z., Chen M., Zhou S., et al.. A novel method for the fabrication of monodisperse hollow silica spheres[J]. Langmuir,2006,22(14):6403-6407.[12] 毛晶.SiO2空心微球的制备与结构表征[D].天津:天津大学,2007.[13] Zhang K., Zheng L.L., Zhang X.H., et al.. SilicaPMMA coreshell and hollow nanospheres[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects,2006,277(3):145-150.[14] 许伟,欧阳申珅,王騊,等.具有微孔、介孔结构SiO2空心球的制备[J].浙江理工大学学报(自然科学版),2016,35(1):22-28. [15] 俞书宏.一种二氧化硅空心球的制备方法:中国,CN1931718A[P].2016-10-09[16] Wan Y., Yu S.H.. Polyelectrolyte controlled largescale synthesis of hollow silica spheres with tunable sizes and wall thicknesses[J]. Journal of Physical Chemistry C,2008,112(10):3641-3647.[17] Nakashima Y., Takai C., RazaviKhosroshahi H., et al.. Control size distribution of hollow silica nanoparticles by viscosity of emulsion template[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects,2016,507(1):164-169.[18] Fuji M., Takai C., Imabeppu H., et al.. Synthesis and shell structure design of hollow silica nanoparticles using polyelectrolyte as template[J]. Journal of Physics(Conference Series),2015,596(1):6591-6596.[19] Zhang J., Lan P.J., Li J., et al.. Solgel derived nearUV and visible antireflection coatings from hybridized hollow silica nanospheres[J]. Journal of SolGel Science and Technology,2014,71(2):267-275.[20] Tao C.Y., Yan H.W., Yuan X.D., et al.. Synthesis of shapecontrolled hollow silica nanostructures with a simple softtemplating method and their application as superhydrophobic antireflective coatings with ultralow refractive indices[J]. Colloids and Surfaces A: Physicochemical Engineering Aspects,2016,501(1):17-23.[21] Ren T., Geng Z., He J., et al.. A versatile route to polymerreinforced, broadband antireflective and superhydrophobic thin films without hightemperature treatment[J]. Journal of Colloid and Interface Science,2017,486(1):1-7.[22] 孙志娟,陈雪莲,蒋春跃.自组装法制备中空二氧化硅纳米粒子减反射薄膜[J].无机材料学报,2014,29(9):947-955.[23] TakaiYamashita C., Imabeppu H., Fuji M.. Synthesis of hollow silica nanoparticles using poly(acrylic acid)-3,3-diaminodipropylamine template[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects,2015,483(2):81-86.[24] Nakashima Y., Takai C., RazaviKhosroshahi H.A., et al.. Effects of primaryand secondaryamines on the formation of hollow silica nanoparticles by using emulsion template method[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects,2016,506(2):849-854.[25] 付宝城.PVC膜/纳米SiO2超疏水表面的构建及其性能研究[D].杭州:浙江理工大学,2015.[26] 陈雪莲.中空二氧化硅纳米粒子制备减反射薄膜的研究[D].杭州:浙江工业大学,2014.[27] Du Y., Luna L.E., Tan W.S., et al.. Hollow silica nanoparticles in UVvisible antireflection coatings for poly (methyl methacrylate) substrates[J]. ACS Nano,2010,4(7):4308-4316. [28] Wang Y.B., Wu J., Wang H.N., et al.. Effective balance of antireflection and selfcleaning properties via hollow silica nanospheresbased surface coated with scattered Titania nanoparticles[J]. Solar Energy,2015,122(3):763-772.[29] TakaiYamashita C., Ando M., Noritake M.A., et al.. Emulsion templating of poly (acrylic acid) by ammonium hydroxide/Sodium hydroxide aqueous mixture for highdispersed hollow silica nanoparticles[J]. Advanced Powder Technology,2017,28(2):398-405.[30] Tsai M.S., Li M.J.. A novel process to prepare a hollow silica sphere via chitosanpolyacrylic acid (CS-PAA) template[J]. Journal of NonCrystalline Solids,2006,352(26/27):2829-2833.[31] Zhang X., Lan P., Lu Y., et al.. Multifunctional antireflection coatings based on novel hollow silicasilica nanocomposites[J]. ACS Applied Materials & Interfaces,2014,6(3):1415-1423.[32] Xu L., He J.. Fabrication of highly transparent superhydrophobic coatings from hollow silica nanoparticles[J]. Langmuir,2012,28(19):7512-7518.[33] Zhang L., Li Y., Sun J., et al.. Layerbylayer fabrication of broadband superhydrophobic antireflection coatings in nearinfrared region[J]. Journal of Colloid and Interface Science,2008,319(1):302-308.[34] Gemici Z., Schwachulla P.I., Williamson E.H., et al.. Targeted functionalization of nanoparticle thin films via capillary condensation[J]. Nano Letters,2009,9(3):1064-1070.

备注/Memo

备注/Memo:
收稿日期:2017-07-21 基金项目:山东省引进国外智力项目(L37002013098);济南市高校院所自主创新计划项目(201303067)作者简介:高英(1991-),女,在读硕士,主要从事金属材料及其表面技术等方面的研究. Email: 2281340741@qq.com 通讯作者*:[HTSS][ZK(]牛玉超(1959-),男,教授,博士,主要从事材料表面技术等方面的研究. Email: niuyuchao@sdjzu.edu.cn
更新日期/Last Update: 2017-09-13